A contact equilibrium may be regarded also as an exchange equilibrium. There is a zero balance of rate of transfer of some quantity between the two systems in contact equilibrium. For example, for a wall permeable only to heat, the rates of diffusion of internal energy as heat between the two systems are equal and opposite. An adiabatic wall between the two systems is 'permeable' only to energy transferred as work; at mechanical equilibrium the rates of transfer of energy as work between them are equal and opposite. If the wall is a simple wall, then the rates of transfer of volume across it are also equal and opposite; and the pressures on either side of it are equal. If the adiabatic wall is more complicated, with a sort of leverage, having an area-ratio, then the pressures of the two systems in exchange equilibrium are in the inverse ratio of the volume exchange ratio; this keeps the zero balance of rates of transfer as work. | A contact equilibrium may be regarded also as an exchange equilibrium. There is a zero balance of rate of transfer of some quantity between the two systems in contact equilibrium. For example, for a wall permeable only to heat, the rates of diffusion of internal energy as heat between the two systems are equal and opposite. An adiabatic wall between the two systems is 'permeable' only to energy transferred as work; at mechanical equilibrium the rates of transfer of energy as work between them are equal and opposite. If the wall is a simple wall, then the rates of transfer of volume across it are also equal and opposite; and the pressures on either side of it are equal. If the adiabatic wall is more complicated, with a sort of leverage, having an area-ratio, then the pressures of the two systems in exchange equilibrium are in the inverse ratio of the volume exchange ratio; this keeps the zero balance of rates of transfer as work. |