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大小无更改 、 2020年11月30日 (一) 19:15
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A contact equilibrium may be regarded also as an exchange equilibrium. There is a zero balance of rate of transfer of some quantity between the two systems in contact equilibrium. For example, for a wall permeable only to heat, the rates of diffusion of internal energy as heat between the two systems are equal and opposite. An adiabatic wall between the two systems is 'permeable' only to energy transferred as work; at mechanical equilibrium the rates of transfer of energy as work between them are equal and opposite. If the wall is a simple wall, then the rates of transfer of volume across it are also equal and opposite; and the pressures on either side of it are equal. If the adiabatic wall is more complicated, with a sort of leverage, having an area-ratio, then the pressures of the two systems in exchange equilibrium are in the inverse ratio of the volume exchange ratio; this keeps the zero balance of rates of transfer as work.
 
A contact equilibrium may be regarded also as an exchange equilibrium. There is a zero balance of rate of transfer of some quantity between the two systems in contact equilibrium. For example, for a wall permeable only to heat, the rates of diffusion of internal energy as heat between the two systems are equal and opposite. An adiabatic wall between the two systems is 'permeable' only to energy transferred as work; at mechanical equilibrium the rates of transfer of energy as work between them are equal and opposite. If the wall is a simple wall, then the rates of transfer of volume across it are also equal and opposite; and the pressures on either side of it are equal. If the adiabatic wall is more complicated, with a sort of leverage, having an area-ratio, then the pressures of the two systems in exchange equilibrium are in the inverse ratio of the volume exchange ratio; this keeps the zero balance of rates of transfer as work.
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接触平衡也可视为交换平衡。在接触平衡状态下,两系统之间某些量的传递速率存在零平衡。例如,对于只能透热的壁,内能作为热在两个系统之间的扩散速率是相等并相反的。两个系统之间的绝热壁只对作为功传递的能量有渗透作用; 在力学平衡,两个系统之间作为功的能量传递速率相等且相反。如果是一个简单的壁,那么通过它的体积转移率也是相等且相反的; 即它两边的压力是相等的。如果绝热壁比较复杂,有一种杠杆,有一个面积比,那么两个体系在交换平衡中的压力与体积交换比成反比,这使得转移率的零平衡作功。
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接触平衡也可视为交换平衡。在接触平衡状态下,两系统之间某些量的传递速率存在零平衡。例如,对于只能透热的壁,内能作为热在两个系统之间的扩散速率是相等并相反的。两个系统之间的绝热壁只对作为功传递的能量有渗透作用; 在机械平衡,两个系统之间作为功的能量传递速率相等且相反。如果是一个简单的壁,那么通过它的体积转移率也是相等且相反的; 即它两边的压力是相等的。如果绝热壁比较复杂,有一种杠杆,有一个面积比,那么两个体系在交换平衡中的压力与体积交换比成反比,这使得转移率的零平衡作功。
     
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