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  | page = 300}}</ref>
 
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'''路德维希·爱德华·玻尔兹曼''' '''Ludwig Eduard Boltzmann'''(1844年2月20日—1906年9月5日),奥地利物理学家、哲学家。他最伟大的功绩是发展了'''统计力学''',并且从统计意义出发解释了'''热力学第二定律'''。1877年,他给出了目前'''熵'''的定义,即'''玻尔兹曼熵公式''':<math>S = k_{\rm B} \ln \Omega \!</math>,将熵解释为系统统计无序性的度量。马克斯·普朗克命名{{math|''k''<sub>B</sub>}}为[[玻尔兹曼常数|'''玻尔兹曼常数 ''']]'''[[Boltzmann constant]]'''。
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'''路德维希·爱德华·玻尔兹曼''' '''Ludwig Eduard Boltzmann'''(1844年2月20日—1906年9月5日),奥地利物理学家、哲学家。他最伟大的功绩是发展了'''统计力学''',并且从统计意义出发解释了'''热力学第二定律'''。1877年,他给出了目前'''熵'''的定义,即'''玻尔兹曼熵公式''':<math>S = k_{\rm B} \ln \Omega \!</math>,将熵解释为系统统计无序性的度量。<ref name="EncycloBritan">{{cite book
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|last1= Klein
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|first1= Martin
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|year= 1970
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|orig-year= 1768
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|chapter= Boltzmann, Ludwig
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|editor1-last= Preece
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|editor1-first= Warren E.
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|title= Encyclopædia Britannica
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|type=hard cover
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|language= English
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|volume= 3
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|edition= Commemorative Edition for Expo 70
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|location= Chicago
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|publisher= William Benton
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|publication-date= 1970
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|page= 893a
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|isbn= 0852291353
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}}
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</ref> 马克斯·普朗克命名{{math|''k''<sub>B</sub>}}为[[玻尔兹曼常数|'''玻尔兹曼常数 ''']]'''Boltzmann constant'''。<ref>{{Citation
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| last = Partington
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| first = J.R.
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| author-link = J.R. Partington
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| title = An Advanced Treatise on Physical Chemistry
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| volume = volume 1, ''Fundamental Principles'', ''The Properties of Gases''
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| place = London
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| publisher = [[Longman|Longmans, Green and Co.]]
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| series =
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| origyear =
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| year = 1949
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| page = 300}}</ref>
    
Statistical mechanics is one of the pillars of modern [[physics]]. It describes how macroscopic observations (such as [[temperature]] and [[pressure]]) are related to microscopic parameters that fluctuate around an average. It connects thermodynamic quantities (such as [[heat capacity]]) to microscopic behavior, whereas, in [[classical thermodynamics]], the only available option would be to measure and tabulate such quantities for various materials.<ref name="gibbs">{{cite book |last=Gibbs |first=Josiah Willard |author-link=Josiah Willard Gibbs |title=Elementary Principles in Statistical Mechanics |year=1902 |publisher=[[Charles Scribner's Sons]] |location=New York |title-link=Elementary Principles in Statistical Mechanics }}</ref>
 
Statistical mechanics is one of the pillars of modern [[physics]]. It describes how macroscopic observations (such as [[temperature]] and [[pressure]]) are related to microscopic parameters that fluctuate around an average. It connects thermodynamic quantities (such as [[heat capacity]]) to microscopic behavior, whereas, in [[classical thermodynamics]], the only available option would be to measure and tabulate such quantities for various materials.<ref name="gibbs">{{cite book |last=Gibbs |first=Josiah Willard |author-link=Josiah Willard Gibbs |title=Elementary Principles in Statistical Mechanics |year=1902 |publisher=[[Charles Scribner's Sons]] |location=New York |title-link=Elementary Principles in Statistical Mechanics }}</ref>
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