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| The mathematics behind the arrow of time, entropy, and basis of the second law of thermodynamics derive from the following set-up, as detailed by Carnot (1824), Clapeyron (1832), and Clausius (1854): | | The mathematics behind the arrow of time, entropy, and basis of the second law of thermodynamics derive from the following set-up, as detailed by Carnot (1824), Clapeyron (1832), and Clausius (1854): |
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− | 时间箭头、熵和热力学第二定律的基础背后的数学来源于以下的设置,详见卡诺(1824)、克拉佩龙(1832)和克劳修斯(1854) :
| + | 时间箭头、熵和热力学第二定律的基础数学背景来源于以下的设置,详见卡诺(1824)、克拉佩龙(1832)和克劳修斯(1854) : |
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| Here, as common experience demonstrates, when a hot body T<sub>1</sub>, such as a furnace, is put into physical contact, such as being connected via a body of fluid (working body), with a cold body T<sub>2</sub>, such as a stream of cold water, energy will invariably flow from hot to cold in the form of heat Q, and given time the system will reach equilibrium. Entropy, defined as Q/T, was conceived by Rudolf Clausius as a function to measure the molecular irreversibility of this process, i.e. the dissipative work the atoms and molecules do on each other during the transformation. | | Here, as common experience demonstrates, when a hot body T<sub>1</sub>, such as a furnace, is put into physical contact, such as being connected via a body of fluid (working body), with a cold body T<sub>2</sub>, such as a stream of cold water, energy will invariably flow from hot to cold in the form of heat Q, and given time the system will reach equilibrium. Entropy, defined as Q/T, was conceived by Rudolf Clausius as a function to measure the molecular irreversibility of this process, i.e. the dissipative work the atoms and molecules do on each other during the transformation. |
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− | 这里,正如常见的经验所证明的,当一个热的物体 t 子1 / 子,例如一个炉子,进入物理接触,例如通过一个流体(工作物体)与一个冷的物体 t 子2 / 子,例如一股冷水,能量总是以热 q 的形式从热流向冷流,并且给定时间系统将达到平衡。熵被定义为 q / t,由 Rudolf Clausius 提出,作为一个函数来衡量这个过程的分子不可逆性。原子和分子在转变过程中相互作用的耗散功。
| + | 这里,如一般经验所示,当热物体T1(例如炉子)通过流体(工作物体)与冷物体T2(例如冷水)物理接触时,能量总是以热 Q 的形式从热的物体流向冷的物体,并且系统将在给定时间内达到平衡。熵定义为 q / t,由 Rudolf Clausius 提出,作为一个函数来衡量这个过程的分子不可逆性,即原子和分子在转变过程中对彼此做的耗散功。 |
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| In this diagram, one can calculate the entropy change ΔS for the passage of the quantity of heat Q from the temperature T<sub>1</sub>, through the "working body" of fluid (see heat engine), which was typically a body of steam, to the temperature T<sub>2</sub>. Moreover, one could assume, for the sake of argument, that the working body contains only two molecules of water. | | In this diagram, one can calculate the entropy change ΔS for the passage of the quantity of heat Q from the temperature T<sub>1</sub>, through the "working body" of fluid (see heat engine), which was typically a body of steam, to the temperature T<sub>2</sub>. Moreover, one could assume, for the sake of argument, that the working body contains only two molecules of water. |
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− | 在这个图中,我们可以计算热量 q 从温度 t1 / sub 通过流体的“工作体”(见热机)到温度 t2 / sub 的熵变 s。此外,为了讨论的目的,我们可以假设工作物体只含有两个水分子。
| + | 在此图中,我们可以计算热量 Q 通过通常是蒸汽的流体的“工作体”(见热机)从温度T1到温度 T2 的熵变 ΔS。此外,为了讨论的目的,可以假设工作物体只含有两个水分子。 |
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| Next, if we make the assignment, as originally done by Clausius: | | Next, if we make the assignment, as originally done by Clausius: |
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| Next, if we make the assignment, as originally done by Clausius: | | Next, if we make the assignment, as originally done by Clausius: |
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− | 接下来,如果我们像最初由克劳修斯所做的那样做作业:
| + | 接下来,如果我们像克劳修斯最初所做的那样: |
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