热力学第二定律的适用性限于接近或处于[https://en.wikipedia.org/wiki/Thermodynamic_equilibrium 平衡状态]的系统。<ref>{{cite journal|last1=Martyushev|first1=L. M.|last2=Seleznev|first2=V. D.|title=The restrictions of the maximum entropy production principle|journal=Physica A: Statistical Mechanics and Its Applications|date=2014|volume=410|doi=10.1016/j.physa.2014.05.014|pages=17–21|arxiv=1311.2068|bibcode=2014PhyA..410...17M}}</ref>同时,支配远非均衡体系的定律仍有待商榷。适用于这种系统原理之一是最大熵产生原理。<ref>{{cite book|last1=Ziegler|first1=H.|title=An Introduction to Thermomechanics|date=1983|location=North Holland, Amsterdam.}}</ref><ref>{{cite journal|last1=Onsager|first1=Lars|title=Reciprocal Relations in Irreversible Processes|journal=Phys. Rev. |volume=37|issue=4|page=405|year=1931|doi=10.1103/PhysRev.37.405|bibcode=1931PhRv...37..405O}}</ref>它要求非平衡系统往熵产生最大化发展。<ref>{{cite book|last1=Kleidon|first1=A.|last2=et.|first2=al.|title=Non-equilibrium Thermodynamics and the Production of Entropy|date=2005|publisher=Springer|location=Heidelberg}}</ref><ref>{{cite journal|last1=Belkin|first1=Andrey|last2=et.|first2=al.|title=Self-assembled wiggling nano-structures and the principle of maximum entropy production|journal=Scientific Reports |date=2015|doi=10.1038/srep08323|pmid=25662746|pmc=4321171|volume=5|pages=8323|bibcode=2015NatSR...5E8323B}}</ref> | 热力学第二定律的适用性限于接近或处于[https://en.wikipedia.org/wiki/Thermodynamic_equilibrium 平衡状态]的系统。<ref>{{cite journal|last1=Martyushev|first1=L. M.|last2=Seleznev|first2=V. D.|title=The restrictions of the maximum entropy production principle|journal=Physica A: Statistical Mechanics and Its Applications|date=2014|volume=410|doi=10.1016/j.physa.2014.05.014|pages=17–21|arxiv=1311.2068|bibcode=2014PhyA..410...17M}}</ref>同时,支配远非均衡体系的定律仍有待商榷。适用于这种系统原理之一是最大熵产生原理。<ref>{{cite book|last1=Ziegler|first1=H.|title=An Introduction to Thermomechanics|date=1983|location=North Holland, Amsterdam.}}</ref><ref>{{cite journal|last1=Onsager|first1=Lars|title=Reciprocal Relations in Irreversible Processes|journal=Phys. Rev. |volume=37|issue=4|page=405|year=1931|doi=10.1103/PhysRev.37.405|bibcode=1931PhRv...37..405O}}</ref>它要求非平衡系统往熵产生最大化发展。<ref>{{cite book|last1=Kleidon|first1=A.|last2=et.|first2=al.|title=Non-equilibrium Thermodynamics and the Production of Entropy|date=2005|publisher=Springer|location=Heidelberg}}</ref><ref>{{cite journal|last1=Belkin|first1=Andrey|last2=et.|first2=al.|title=Self-assembled wiggling nano-structures and the principle of maximum entropy production|journal=Scientific Reports |date=2015|doi=10.1038/srep08323|pmid=25662746|pmc=4321171|volume=5|pages=8323|bibcode=2015NatSR...5E8323B}}</ref> |