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| The complete state of the mechanical system at a given time, mathematically encoded as a phase point (classical mechanics) or a pure quantum state vector (quantum mechanics). | | The complete state of the mechanical system at a given time, mathematically encoded as a phase point (classical mechanics) or a pure quantum state vector (quantum mechanics). |
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− | 机械系统在给定时间内的完整状态,用数学编码表示为相位点(经典力学)或纯量子态矢量(量子力学)。
| + | 力学系统在给定时间内的完整状态,用数学表示为相空间中的点(经典力学)或纯量子态矢量(量子力学)。 |
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| # An equation of motion which carries the state forward in time: [[Hamilton's equations]] (classical mechanics) or the [[time-dependent Schrödinger equation]] (quantum mechanics) | | # An equation of motion which carries the state forward in time: [[Hamilton's equations]] (classical mechanics) or the [[time-dependent Schrödinger equation]] (quantum mechanics) |
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| An equation of motion which carries the state forward in time: Hamilton's equations (classical mechanics) or the time-dependent Schrödinger equation (quantum mechanics) | | An equation of motion which carries the state forward in time: Hamilton's equations (classical mechanics) or the time-dependent Schrödinger equation (quantum mechanics) |
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− | 一个运动方程推动状态向前的时间: 哈密尔顿方程(经典力学)或随时间变化的薛定谔方程方程(量子力学)
| + | 一个运动方程描述状态在时间上的演化: 哈密尔顿方程(经典力学)或含时薛定谔方程(量子力学) |
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| Using these two concepts, the state at any other time, past or future, can in principle be calculated. | | Using these two concepts, the state at any other time, past or future, can in principle be calculated. |
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| Using these two concepts, the state at any other time, past or future, can in principle be calculated. | | Using these two concepts, the state at any other time, past or future, can in principle be calculated. |
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− | 使用这两个概念,在任何其他时间,过去或未来的状态,原则上都可以计算出来。
| + | 使用这两个概念,系统在任何时间的状态,无论过去或未来,原则上都可以计算出来。 |
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| There is however a disconnection between these laws and everyday life experiences, as we do not find it necessary (nor even theoretically possible) to know exactly at a microscopic level the simultaneous positions and velocities of each molecule while carrying out processes at the human scale (for example, when performing a chemical reaction). Statistical mechanics fills this disconnection between the laws of mechanics and the practical experience of incomplete knowledge, by adding some uncertainty about which state the system is in. | | There is however a disconnection between these laws and everyday life experiences, as we do not find it necessary (nor even theoretically possible) to know exactly at a microscopic level the simultaneous positions and velocities of each molecule while carrying out processes at the human scale (for example, when performing a chemical reaction). Statistical mechanics fills this disconnection between the laws of mechanics and the practical experience of incomplete knowledge, by adding some uncertainty about which state the system is in. |
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| There is however a disconnection between these laws and everyday life experiences, as we do not find it necessary (nor even theoretically possible) to know exactly at a microscopic level the simultaneous positions and velocities of each molecule while carrying out processes at the human scale (for example, when performing a chemical reaction). Statistical mechanics fills this disconnection between the laws of mechanics and the practical experience of incomplete knowledge, by adding some uncertainty about which state the system is in. | | There is however a disconnection between these laws and everyday life experiences, as we do not find it necessary (nor even theoretically possible) to know exactly at a microscopic level the simultaneous positions and velocities of each molecule while carrying out processes at the human scale (for example, when performing a chemical reaction). Statistical mechanics fills this disconnection between the laws of mechanics and the practical experience of incomplete knowledge, by adding some uncertainty about which state the system is in. |
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− | 然而,这些定律与日常生活经验之间存在脱节,因为我们认为,在人类尺度上进行过程(例如,进行化学反应时)时,没有必要(甚至在理论上也不可能)在微观层面上准确地知道每个分子同时存在的位置和速度。统计力学填补了力学定律和不完全知识的实践经验之间的这种脱节,通过增加一些不确定性,系统处于何种状态。
| + | 然而,这些定律与日常生活经验之间存在脱节。因为对于在人类尺度上进行过程(例如化学反应),我们没有必要(甚至在理论上也不可能)在微观层面上准确地知道每个分子所在的位置及其速度。统计力学通过增加一些对于系统状态的不确定性,填补了力学定律和不完全知识的实践经验之间的这种脱节,。 |
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| Whereas ordinary mechanics only considers the behaviour of a single state, statistical mechanics introduces the statistical ensemble, which is a large collection of virtual, independent copies of the system in various states. The statistical ensemble is a probability distribution over all possible states of the system. In classical statistical mechanics, the ensemble is a probability distribution over phase points (as opposed to a single phase point in ordinary mechanics), usually represented as a distribution in a phase space with canonical coordinates. In quantum statistical mechanics, the ensemble is a probability distribution over pure states, and can be compactly summarized as a density matrix. | | Whereas ordinary mechanics only considers the behaviour of a single state, statistical mechanics introduces the statistical ensemble, which is a large collection of virtual, independent copies of the system in various states. The statistical ensemble is a probability distribution over all possible states of the system. In classical statistical mechanics, the ensemble is a probability distribution over phase points (as opposed to a single phase point in ordinary mechanics), usually represented as a distribution in a phase space with canonical coordinates. In quantum statistical mechanics, the ensemble is a probability distribution over pure states, and can be compactly summarized as a density matrix. |
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− | 普通力学只考虑单一状态的行为,而统计力学引入了系综系统,它是系统在不同状态下的大量虚拟、独立副本的集合。系综是一个覆盖系统所有可能状态的概率分布。在经典的统计力学中,系综是相点上的概率分布(与普通力学中的单相点相反) ,通常表现为相空间中的正则坐标分布。在量子统计力学中,系综是纯态上的概率分布,可以简单地概括为密度矩阵。
| + | 普通力学只考虑单一状态的行为,而统计力学引入了统计系综,它是系统在各种状态下的大量虚拟、独立副本的集合。系综是一个覆盖系统所有可能状态的概率分布。在经典的统计力学中,系综是相点上的概率分布(与普通力学中的单相点相反) ,通常表现为正则坐标下相空间中的分布。在量子统计力学中,系综是纯态上的概率分布,可以简单地概括为密度矩阵。 |
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| As is usual for probabilities, the ensemble can be interpreted in different ways: | | As is usual for probabilities, the ensemble can be interpreted in different ways: |
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− | 与通常的概率一样,这个总体可以用不同的方式来解释:
| + | 与通常的概率一样,系综可以用不同的方式来解释: |
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| + | * an ensemble can be taken to represent the various possible states that a ''single system'' could be in ([[epistemic probability]], a form of knowledge), or |
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| + | * the members of the ensemble can be understood as the states of the systems in experiments repeated on independent systems which have been prepared in a similar but imperfectly controlled manner ([[empirical probability]]), in the limit of an infinite number of trials. |
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| * an ensemble can be taken to represent the various possible states that a ''single system'' could be in ([[epistemic probability]], a form of knowledge), or | | * an ensemble can be taken to represent the various possible states that a ''single system'' could be in ([[epistemic probability]], a form of knowledge), or |
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| 合奏的一个特殊类别是那些不随时间演变的合奏。这些系综称为平衡系综,它们的状态称为统计平衡。如果对于集合中的每个状态,集合也包含其所有的未来和过去状态,其概率等于处于该状态的概率,则出现统计平衡。孤立系统的平衡系综是统计热力学研究的重点。非平衡统计力学解决了更一般的情况下的系综,随着时间的推移而改变,和 / 或非孤立系统的系综。 | | 合奏的一个特殊类别是那些不随时间演变的合奏。这些系综称为平衡系综,它们的状态称为统计平衡。如果对于集合中的每个状态,集合也包含其所有的未来和过去状态,其概率等于处于该状态的概率,则出现统计平衡。孤立系统的平衡系综是统计热力学研究的重点。非平衡统计力学解决了更一般的情况下的系综,随着时间的推移而改变,和 / 或非孤立系统的系综。 |
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| == Statistical thermodynamics == | | == Statistical thermodynamics == |