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删除478字节 、 2020年10月11日 (日) 21:48
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which is the basis of the accurate determination of the absolute entropy of pure substances from measured heat capacity curves and entropy changes at phase transitions, i.e. by calorimetry.[16] [11] Introducing a set of internal variables {\displaystyle \xi }\xi  to describe the deviation of a thermodynamic system in physical equilibrium (with the required well-defined uniform pressure P and temperature T)[15] from the chemical equilibrium state, one can record the equality
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