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== Gas molecules 气体分子 ==
 
== Gas molecules 气体分子 ==
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[[Image:Degrees of freedom (diatomic molecule).png|thumb|right|Different ways of visualizing the 6 degrees of freedom of a diatomic molecule. (CM: [[center of mass]] of the system, T: [[translational motion]], R: [[rotation]]al motion, V: [[molecular vibration|vibrational motion]].)]]
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[[文件:Degrees of freedom (diatomic molecule).png|缩略图||可视化双原子分子六个自由度的不同方式。(其中CM:系统的质心,T:平移运动,R:旋转运动,V:振动运动。)]]
 
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Different ways of visualizing the 6 degrees of freedom of a diatomic molecule. (CM: [[center of mass of the system, T: translational motion, R: rotational motion, V: vibrational motion.)]]
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用不同的方式可视化双原子分子的6个自由度。(CM: [系统的质心,t: 平动运动,r: 旋转轴,v: 振动运动]]
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In three-dimensional space, three degrees of freedom are associated with the movement of a particle. A diatomic gas molecule has 6 degrees of freedom{{Dubious|reason=diatomic molecules have at most 6, usually 5|date=April 2017}}. This set may be decomposed in terms of translations, rotations, and [[molecular vibration|vibrations]] of the molecule. The [[center of mass]] motion of the entire molecule accounts for 3 degrees of freedom. In addition, the molecule has two [[rotation]]al degrees of motion and one{{Dubious|reason=diatomic molecules have at most 1, usually zero vibrational modes|date=April 2017}} [[vibrational mode]]. The rotations occur around the two axes perpendicular to the line between the two atoms. The rotation around the atom–atom bond is not a physical rotation{{Dubious|reason=Diatomic molecules rotate and precess|date=April 2017}}. This yields, for a diatomic molecule, a decomposition of:
 
In three-dimensional space, three degrees of freedom are associated with the movement of a particle. A diatomic gas molecule has 6 degrees of freedom{{Dubious|reason=diatomic molecules have at most 6, usually 5|date=April 2017}}. This set may be decomposed in terms of translations, rotations, and [[molecular vibration|vibrations]] of the molecule. The [[center of mass]] motion of the entire molecule accounts for 3 degrees of freedom. In addition, the molecule has two [[rotation]]al degrees of motion and one{{Dubious|reason=diatomic molecules have at most 1, usually zero vibrational modes|date=April 2017}} [[vibrational mode]]. The rotations occur around the two axes perpendicular to the line between the two atoms. The rotation around the atom–atom bond is not a physical rotation{{Dubious|reason=Diatomic molecules rotate and precess|date=April 2017}}. This yields, for a diatomic molecule, a decomposition of:
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==Independent degrees of freedom==
 
==Independent degrees of freedom==
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