| Thus, as <math>r\rightarrow \infty</math> in any fixed thermodynamic state (fixed t) near the critical point, <math>h</math> decays with increasing <math>r</math> proportionally to <math>r^{-\frac{1}{2}(d-1)}e^{-r/\xi}\ ,</math> as in the [https://en.wikipedia.org/wiki/Ornstein%E2%80%93Zernike_equation?oldformat=true '''Ornstein-Zernike theory''']. If, instead, the critical point is approached <math>(\xi \rightarrow \infty)</math> with a fixed, large <math>r\ ,</math> we have <math>h(r)</math> decaying with <math>r</math> only as an inverse power, <math>r^{-(d-2+\eta)}\ ,</math> which corrects the <math>r^{-(d-2)}</math> that appears in the Ornstein-Zernike theory in that limit. The scaling law({{EquationNote|1=10}}) with scaling function <math>G(x)</math> interpolates between these extremes. | | Thus, as <math>r\rightarrow \infty</math> in any fixed thermodynamic state (fixed t) near the critical point, <math>h</math> decays with increasing <math>r</math> proportionally to <math>r^{-\frac{1}{2}(d-1)}e^{-r/\xi}\ ,</math> as in the [https://en.wikipedia.org/wiki/Ornstein%E2%80%93Zernike_equation?oldformat=true '''Ornstein-Zernike theory''']. If, instead, the critical point is approached <math>(\xi \rightarrow \infty)</math> with a fixed, large <math>r\ ,</math> we have <math>h(r)</math> decaying with <math>r</math> only as an inverse power, <math>r^{-(d-2+\eta)}\ ,</math> which corrects the <math>r^{-(d-2)}</math> that appears in the Ornstein-Zernike theory in that limit. The scaling law({{EquationNote|1=10}}) with scaling function <math>G(x)</math> interpolates between these extremes. |
− | 因此,在任何靠近临界点的恒温热力学状态下,当<math>r\rightarrow \infty</math>时,<math>h</math>随<math>r</math>的增加依<math>r^{-\frac{1}{2}(d-1)}e^{-r/\xi}\ </math>成比例衰减(参见'''[https://en.wikipedia.org/wiki/Ornstein%E2%80%93Zernike_equation? 奥恩斯泰因-泽尔尼克理论 Ornstein-Zernike theory]''')。 | + | 因此,在任何靠近临界点的恒温热力学状态下,当<math>r\rightarrow \infty</math>时,<math>h</math>随<math>r</math>的增加依<math>r^{-\frac{1}{2}(d-1)}e^{-r/\xi}\ </math>成比例衰减(参见'''[https://en.wikipedia.org/wiki/Ornstein%E2%80%93Zernike_equation? 奥恩斯泰因-泽尔尼克理论 Ornstein-Zernike theory]''')。如果相反,在固定的大<math>r\ </math>条件下,迫近临界点(<math>(\xi \rightarrow \infty)</math>),会有<math>h(r)</math>作为逆幂<math>r^{-(d-2+\eta)}\ </math>随<math>r</math>衰减,这也修正了在此极限条件下奥恩斯泰因-泽尔尼克理论中出现的<math>r^{-(d-2)}</math>。标度律({{EquationNote|1=10}})及标度函数<math>G(x)</math>内插于这些极限之间。 |
| In the language of fluids, with <math>\rho</math> the number density and <math>\chi</math> the isothermal compressibility, we have as an exact relation in the Ornstein-Zernike theory | | In the language of fluids, with <math>\rho</math> the number density and <math>\chi</math> the isothermal compressibility, we have as an exact relation in the Ornstein-Zernike theory |