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| For example, one widely cited writer, H. B. Callen writes in this context: "In actuality, few systems are in absolute and true equilibrium." He refers to radioactive processes and remarks that they may take "cosmic times to complete, [and] generally can be ignored". He adds "In practice, the criterion for equilibrium is circular. Operationally, a system is in an equilibrium state if its properties are consistently described by thermodynamic theory!" | | For example, one widely cited writer, H. B. Callen writes in this context: "In actuality, few systems are in absolute and true equilibrium." He refers to radioactive processes and remarks that they may take "cosmic times to complete, [and] generally can be ignored". He adds "In practice, the criterion for equilibrium is circular. Operationally, a system is in an equilibrium state if its properties are consistently described by thermodynamic theory!" |
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− | 例如,一位被广泛引用的作家'''<font color="#ff8000">H.B.卡伦 H.B.Callen</font>'''在这里写道: “实际上,很少有系统处于绝对和真正的平衡状态。”他提到了放射性过程和评论,认为它们可能需要“宇宙时间才能完成,而且通常可以忽略”。他补充道: “在实践中,平衡的标准是循环的。在操作上,如果一个系统的性质一致地用热力学理论来描述,那么它就处于平衡状态! ” | + | 例如,一位被广泛引用的作家'''<font color="#ff8000">H.B.卡伦 H.B.Callen</font>'''在这里写道: “实际上,很少有系统处于绝对和真正的平衡状态。”他提到了放射性过程,认为它们可能需要“宇宙时间才能完成,因此通常可以忽略”。他补充道: “在实践中,平衡的标准是循环的。在操作上,如果一个系统的性质一致地用热力学理论来描述,那么它就处于平衡状态! ” |
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| Another author, cited by Callen as giving a "scholarly and rigorous treatment", and cited by Adkins as having written a "classic text", A.B. Pippard writes in that text: "Given long enough a supercooled vapour will eventually condense, ... . The time involved may be so enormous, however, perhaps 10<sup>100</sup> years or more, ... . For most purposes, provided the rapid change is not artificially stimulated, the systems may be regarded as being in equilibrium." | | Another author, cited by Callen as giving a "scholarly and rigorous treatment", and cited by Adkins as having written a "classic text", A.B. Pippard writes in that text: "Given long enough a supercooled vapour will eventually condense, ... . The time involved may be so enormous, however, perhaps 10<sup>100</sup> years or more, ... . For most purposes, provided the rapid change is not artificially stimulated, the systems may be regarded as being in equilibrium." |
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− | Callen引用另一位作者的话说,他给出了“学术性和严谨的论述” ,Adkins引用他的话说,他写了一本“经典著作”—— '''<font color="#ff8000">A.B.皮帕德 A.B.Pippard</font>'''在文中写道: “只要时间足够长,过冷水蒸汽最终会凝结,... ..。时间可能是巨大的,然而,也许10年或者更长的时间。就大多数目的而言,只要这种迅速的变化不是人为地刺激,这些系统就可以被视为处于平衡状态。”
| + | Callen引用另一位作者的话说,他给出了“学术且严谨的论述” ,Adkins引用他的话说,他写了一本“经典著作”—— '''<font color="#ff8000">A.B.皮帕德 A.B.Pippard</font>'''在文中写道: “只要时间足够长,过冷水蒸汽最终会凝结,... ..。时间可能是巨大的,也许长达10年或者更长。就大多数目的而言,只要这种迅速的变化不是人为地刺激,这些系统就可以被视为处于平衡状态。” |
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| Another author, A. Münster, writes in this context. He observes that thermonuclear processes often occur so slowly that they can be ignored in thermodynamics. He comments: "The concept 'absolute equilibrium' or 'equilibrium with respect to all imaginable processes', has therefore, no physical significance." He therefore states that: "... we can consider an equilibrium only with respect to specified processes and defined experimental conditions." | | Another author, A. Münster, writes in this context. He observes that thermonuclear processes often occur so slowly that they can be ignored in thermodynamics. He comments: "The concept 'absolute equilibrium' or 'equilibrium with respect to all imaginable processes', has therefore, no physical significance." He therefore states that: "... we can consider an equilibrium only with respect to specified processes and defined experimental conditions." |
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− | 另一位作者A. Münster就是在这种背景下写作的。他观察到热核反应发生的速度非常缓慢,以至于在热力学中可以忽略不计。他评论道: “‘绝对平衡’或‘所有可想象过程的平衡’的概念,因此没有物理意义。”因此他说: “ ... 我们只能考虑特定过程和确定的实验条件下的平衡。” | + | 另一位作者A.Münster,写在这种情况下。他观察到热核反应发生的速度非常缓慢,以至于在热力学中可以忽略不计。他评论道: “‘绝对平衡’或‘所有可想象过程的平衡’的概念没有物理意义。”他说: “ ... 我们只能考虑特定过程和确定的实验条件下的平衡。” |
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| 根据'''<font color="#ff8000">L.缇莎 L.Tisza</font>'''的说法: “ ... 在讨论接近绝对零度的现象时。经典理论的绝对预测变得特别模糊,因为在非平衡状态下发生冻结是非常普遍的。” | | 根据'''<font color="#ff8000">L.缇莎 L.Tisza</font>'''的说法: “ ... 在讨论接近绝对零度的现象时。经典理论的绝对预测变得特别模糊,因为在非平衡状态下发生冻结是非常普遍的。” |
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| ==Definitions== | | ==Definitions== |