A thermodynamic system consisting of a single phase in the absence of external forces, in its own internal thermodynamic equilibrium, is homogeneous.<ref name="Planck 1903 3"/> This means that the material in any small volume element of the system can be interchanged with the material of any other geometrically congruent volume element of the system, and the effect is to leave the system thermodynamically unchanged. In general, a strong external force field makes a system of a single phase in its own internal thermodynamic equilibrium inhomogeneous with respect to some [[Intensive and extensive properties|intensive variables]]. For example, a relatively dense component of a mixture can be concentrated by centrifugation. | A thermodynamic system consisting of a single phase in the absence of external forces, in its own internal thermodynamic equilibrium, is homogeneous.<ref name="Planck 1903 3"/> This means that the material in any small volume element of the system can be interchanged with the material of any other geometrically congruent volume element of the system, and the effect is to leave the system thermodynamically unchanged. In general, a strong external force field makes a system of a single phase in its own internal thermodynamic equilibrium inhomogeneous with respect to some [[Intensive and extensive properties|intensive variables]]. For example, a relatively dense component of a mixture can be concentrated by centrifugation. |