| To consider the notion of fluctuations in an isolated thermodynamic system, a convenient example is a system specified by its extensive state variables, internal energy, volume, and mass composition. By definition they are time-invariant. By definition, they combine with time-invariant nominal values of their conjugate intensive functions of state, inverse temperature, pressure divided by temperature, and the chemical potentials divided by temperature, so as to exactly obey the laws of thermodynamics.<ref>Tschoegl, N.W. (2000). ''Fundamentals of Equilibrium and Steady-State Thermodynamics'', Elsevier, Amsterdam, {{ISBN|0-444-50426-5}}, p. 21.</ref> But the laws of thermodynamics, combined with the values of the specifying extensive variables of state, are not sufficient to provide knowledge of those nominal values. Further information is needed, namely, of the constitutive properties of the system. | | To consider the notion of fluctuations in an isolated thermodynamic system, a convenient example is a system specified by its extensive state variables, internal energy, volume, and mass composition. By definition they are time-invariant. By definition, they combine with time-invariant nominal values of their conjugate intensive functions of state, inverse temperature, pressure divided by temperature, and the chemical potentials divided by temperature, so as to exactly obey the laws of thermodynamics.<ref>Tschoegl, N.W. (2000). ''Fundamentals of Equilibrium and Steady-State Thermodynamics'', Elsevier, Amsterdam, {{ISBN|0-444-50426-5}}, p. 21.</ref> But the laws of thermodynamics, combined with the values of the specifying extensive variables of state, are not sufficient to provide knowledge of those nominal values. Further information is needed, namely, of the constitutive properties of the system. |