The historical origin of the second law of thermodynamics was in Carnot's principle. It refers to a cycle of a Carnot heat engine, fictively operated in the limiting mode of extreme slowness known as quasi-static, so that the heat and work transfers are between subsystems that are always in their own internal states of thermodynamic equilibrium. The Carnot engine is an idealized device of special interest to engineers who are concerned with the efficiency of heat engines. Carnot's principle was recognized by Carnot at a time when the caloric theory of heat was seriously considered, before the recognition of the first law of thermodynamics, and before the mathematical expression of the concept of entropy. Interpreted in the light of the first law, it is physically equivalent to the second law of thermodynamics, and remains valid today. Carnot's original arguments were made from the viewpoint of the caloric theory, before the discovery of the first law of thermodynamics. Some samples from his book are: | The historical origin of the second law of thermodynamics was in Carnot's principle. It refers to a cycle of a Carnot heat engine, fictively operated in the limiting mode of extreme slowness known as quasi-static, so that the heat and work transfers are between subsystems that are always in their own internal states of thermodynamic equilibrium. The Carnot engine is an idealized device of special interest to engineers who are concerned with the efficiency of heat engines. Carnot's principle was recognized by Carnot at a time when the caloric theory of heat was seriously considered, before the recognition of the first law of thermodynamics, and before the mathematical expression of the concept of entropy. Interpreted in the light of the first law, it is physically equivalent to the second law of thermodynamics, and remains valid today. Carnot's original arguments were made from the viewpoint of the caloric theory, before the discovery of the first law of thermodynamics. Some samples from his book are: |